Alkylene Oxides and Their Polymers by F.E. Bailey

By F.E. Bailey

A entire remedy of a big kinfolk of polymers important in a variety of purposes in such fields as car, pharmaceutical, beauty, metal-working, mining, commercial coating, fabric, development, and residential furniture. Summarizes the chemistry and mechanisms; presents simple prepa

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22. B. L. Van Duuren, L. Langseth, B. M. Goldschmidt, and L. Orris, J. Nat. Cancer Inst. 39 (6):1217 (Dec. 1967). Bibliography S. A. Cogswell, ''Ethylene Oxide, Marketing Research Report," in Chemical Economics Handbook, SRI International, Menlo Park, 1986. A. O. Masilungen, "Propylene Oxide, Marketing Report," in Chemical Economics Handbook, SRI International, Menlo Park, 1984. Page 26 Glycols (G. O. ), Reinhold Publishing Company, ACS Monograph Series, New York, 1952. Y. Okamoto, Polymer Preprints 25:264 (1984); S.

5. 1047. 6. OSHA, 53 Federal Register 11414 (4/6/88); J. Coatings Tech. 60 (7):20 (1988). 7. G. D. Clayton and F. E. Clayton, Patty's Hygiene and Toxicology, V2B, Toxicology, John Wiley & Sons, New York, 1981, p. 3109. Page 25 8. K. M. :78–83 (October 1988). 9. A. Phatak, C. M. Burns, and R. Y. N. Huang, J. Appl. Polymer Sci. 34:1835 (1987). 10. T. L. Caskey, Mod. Plastics 45:148 (1967). 11. Imperial Chemical Ind. , The Handling and Storage of Ethylene Oxide, CPP4, The Chemical Industries Safety & Health Council of the Chemical Industries Association, London, August 1975.

G. Farbenindustrie, AG (13). It was during the 1940s that the base-initiated polymerization of propylene oxide began to be used to produce products that are still in use today (14). In a series of patents by H. R. Rife and F. H. Roberts (15), poly (propylene oxide)s are described that are initiated in the presence of alcohols to produce ether propoxylates. These liquid polymers had methoxy or butoxy groups on one end of the polyether chain and were used as lubricants and hydraulic fluids. This work was quickly followed by other derivatives, which included esters and mixed alkoxylates of propylene oxide and ethylene oxide (16).

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